Pigment Ink Safety Data

According to Regulation (EC) No. 1907/2006

Date 28.02.2023

1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

1.1 Product identifiers Product name: Aqueous Pigment ink

1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Inkjet printing Uses advised against: None known.

1.3 Details of the supplier of the safety data sheet 

2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008

2.2 Label elements Labeling according to Regulation (EC) No. 1272/2008 The mixture has not to be labeled as hazardous according to Regulation (EC) no. 1272/2008. Hazard pictograms: None Signal word: None Hazard statement(s): None Precautionary statement(s): None

2.3 Other hazards No information available.

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Mixture General information: Organic dye stuffs, organic solvents and additives solubilized in water.

Information on components:

Chemical Name CAS-No. EC-No. % [w/w] Classification according to Regulation (EC) No.1272/2008 (CLP)

Glycerol 56-81-5 200-289-5 < 20 Eye Irrit. 1: H318

Diethylene glycol 111-46-6 203-872-2 < 10 Eye Irrit. 1; H318

Butoxytriglycol 143-22-6 203-961-6 < 3 Acute Tox. 4; H30 Skin Sens 2; H315 Eye Irrit. 1; H318

C.I.77726/Carbon Black 1333-86-4 215-609-9 < 5 Acute Tox. 4; H30 Skin Sens 2; H315

Pigment Blue 15:3 C.I. 74160 147-14-8 205-685-1 < 5 Acute Tox. 4; H30 Skin Sens 2; H315 C.I.

Pigment Red 122 (C.I.73915) 980-26-7 213-561-3 < 5 Acute Tox. 4; H30 Skin Sens 2; H315 C.I.

Pigment Yellow 74 6358-31-2 228-768-4 < 5 Acute Tox. 4; H30 Skin Sens 2; H315

Pigment Blue 15:3 C.I. 74160 147-14-8 205-685-1 < 1 Acute Tox. 4; H30 Skin Sens 2; H315 C.I.

Pigment Red 122 (C.I.73915) 980-26-7 213-561-3 < 1 Acute Tox. 4; H30 Skin Sens 2; H315

Water 7732-18-5 - < 70 Not classified 4.

4. FIRST AID MEASURES

4.1 Description of first aid measures Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Skin contact: Immediately flush with plenty of water while removing contaminated clothing and shoes. Wash contaminated clothing before reuse. If swelling or redness occurs, call a physician. Eye Contact: Do not rub eyes. Immediately flush eyes with plenty of water at least 15 minutes. Hold eyelids open during flushing. Call a physician. Ingestion: If swallowed, do not induce vomiting. Seek immediate medical advice.

4.2 Most important symptoms and effects, both acute and delayed No data available.

4.3 Indication of any immediate medical attention and special treatment needed No data available.

5. FIRE FIGHTING MEASURES 消防措施

5.1 Extinguishing media Suitable extinguishing media: Use Dry chemical or CO2.

Unsuitable extinguishing media: None known.

5.2 Special hazards arising from the substance or mixture Exposure to decomposition products may cause a health hazard.

5.3 Advice for fire fighters No data available.

6. ACCIDENTAL RELEASE MEASURES 意外释放的措施

6.1 Personal precautions, protective equipment and emergency procedures Wear appropriate personal protective equipment like safety glasses, gloves and clothes (see section8). Avoid dust formation. Avoid breathing vapors, mist or gas.

6.2 Environmental precautions Do not flush into surface water or sanitary sewer system.

6.3 Methods and materials for containment and cleaning up Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand ordiatomaceous earth, commercial sorbents, or recover using pumps. Keep in suitable, closed containers for disposal.

6.4 Reference to other sections For disposal see section 13.

7. HANDLING AND STORAGE 处理和存储

7.1 Precautions for safe handling Handle with the usual precautions for industrial chemical. Avoid contact with skin, eyes and clothing.

7.2 Conditions for safe storage, including any incompatibilities Do not store the product in high or freezing temperatures. Keep the product out of direct sunlight. Do not store the product with oxidizing agents or explosives.

7.3 Specific end uses No data available.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION 暴露控制/人员保护

8.1 Control parameters Components with workplace control parameters Glycerol (CAS 56-81-5): MAK Short-term value: no data available, inhalable aerosol (Germany, Switzerland) Long-term value: no data available, inhalable aerosol (Germany, Switzerland) DNEL Employee, long-term exposure, systemic effects, dermal: 33mg/m³ Employee, long-term exposure, systemic effects, inhalation: 56mg/ m³ Consumer, long-term exposure, systemic effects, dermal: no data available Consumer, long-term exposure, systemic effects, inhalation: 33mg/m³ PNEC Freshwater: 0.885mg/l Marine water: 0.0885mg/l Intermittent release: 8.85mg/l STP: 1000mg/l Sediment (freshwater): 3.3mg/kg Soil: 0.141mg/kg All “MAK” values concerning the workplace parameters are according to the following national Institutions: AUVA (Austria), Belgian Federal Public Service Employment,Labour and Social Dialque (Belgium),ENI Corporate (Italy), Eurofins Danmarks A/S (Denmark), FIOH (Finland), HSL (Great Britain), INRS(France), ITM (Sweden), INSHT (Spain), NIOM (Poland), NFSZ (Hungary), SUVA (Switzerland), DFG(Germany)

8.2 Exposure controls Appropriate engineering controls: Use in a well ventilated area. Personal protective equipment Eye/face protection: Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN166(EU). Skin protection: Handle with gloves. Gloves must be inspected prior to use.Use proper glove removal technique (without touching glove'souter surface) to avoid skin contact with this product. Disposeof contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dryhands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection: Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection: Respiratory protection is not required. Where protection fromnuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hygiene measures: Handle in accordance with good industrial hygiene and safetypractice.

9. PHYSICAL AND CHEMICAL PROPERTIES（物理、化学性质）

9.1 Information on basic physical and chemical properties Appearance: Physical state: Liquid Color: Black / Cyan / Magenta / Yellow/Light Cyan/Light Magenta Odor: No information available Odor Odor Threshold: No data available PH: 7.0-10.0 at 20°C / 68°F Melting point/freezing point: No data available Initial boiling point and boiling range: Not determined Flash point: Not detected until 95°C / 203°F (close cup, ASTM D3278) Evaporation rate: Not determined Flammability (solid, gas): No data available Upper/lower flammability or explosive limits: Lower limit: Not determined Upper limit: Not determined Vapour pressure: No data available Vapour density: No data available Relative density: 1.08 at 20°C / 68°F Water solubility: Complete Partition coefficient, n-octanol/water: No data available Auto-ignition temperature: No data available Decomposition temperature: No data available Viscosity (kinematic): Less than 5mPa’s Explosive properties: No data available Oxidizing properties: No data available

9.2 Other safety information No relevant additional information available.

10. STABILITY AND REACTIVITY（稳定性、反应性）

10.1 Reactivity No reactivity under normal temperature.

10.2 Chemical stability Stable under normal temperature.

10.3 Possibility of hazardous reactions No expected.

10.4 Conditions to avoid High and freezing temperature.

10.5 Incompatible materials Oxidizers and explosives.

10.6 Hazardous decomposition products None under normal temperature.

11. TOXICOLOGICAL INFORMATION（毒性资料）

11.1 Information on toxicological effects Acute toxicity Oral LD50: >5000mg/kg(rats). Acute toxicity Dermal LD50: >2000mg/kg(rats). Irritation Eye: No data available Irritation Skin: No data available  Corrosivity: No data available Sensitization: No data available Carcinogenicity: No data available Mutagenicity: No data available Reproduction toxicity: No data available

12. ECOLOGICAL INFORMATION 生态信息

12.1 Toxicity There are no data available for the mixture itself. Information on components under section 3: Glycerol: Acute toxicity: Fish: LC50 >27860mg/l (Pimephalespromelas; 96h) Daphnia and aquatic invertebrates: EC50 >100mg/l (Daphnia magna; 48h) Alga: EC5>10000mg/l (Scenedesmusquadricauda; 192h) Glycerol: Acute toxicity: Fish: LC50 >54000mg/l (Oncorhynchus mykiss; 96h) Daphnia and aquatic invertebrates: EC50 >10000mg/l (Daphnia magna; 24h) Alga: EC3>10000mg/l (Scenedesmusquadricauda; 192h)

12.2 Persistence and degradability There are no data available for the mixture itself. Information on components under section 3: Ethylene glycol: Readily biodegradable. Glycerol: Readily biodegradable.

12.3 Bio accumulative potential No data available.

12.4 Mobility in soil No data available.

12.5 Results of PBT and vPvB assessment This mixture contains no substances which are assessed as PBT or vPvB.

12.6 Other adverse effects No data available.

12.7 Additional Information No data available. 13. DISPOSAL CONSIDERATIONS 处理事项 13.1 Waste treatment methods Product: Disposal should be in accordance with local, state or national legislation. For example: by incineration in a suitable plant.

13. DISPOSAL CONSIDERATIONS 处理事项

13.1 Waste treatment methods

14. TRANSPORT INFORMATION 运输 Not classified as dangerous for ADR/RID, ADR/ADNR, IMDG, IATA.

14.1 UN number Not applicable.

14.2 UN proper shipping name Not applicable.

14.3 Transport hazard class(es) Not applicable.

14.4 Packaging group Not applicable.

14.5 Environmental hazards Not applicable.

14.6 Special precautions for user Not applicable.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not available.

15. REGULATORY INFORMATION This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 and theirchanges.

15.1 Safety, health and environmental regulations/legislation specific for the substance ormixture Not available.

15.2 Chemical Safety Assessment Not available.

16. OTHER INFORMATION

Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. The users working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified under section 1 without first obtaining written handling instruction. It always the responsibility of the user to take all necessary steps in order to fulfill the demand laid down in the local rules and legislation. It does not represent any guarantee of the properties of the product. . JOB and its affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. List of abbreviations and acronyms that may be but not necessarily used in this safety datasheet:

ACGIH: American Conference of Governmental Industrial Hygienists BEI: BiologischerExpositionsindex BAT: BiologischerArbeitsstoff-Toleranzwert (biological tolerance value) CAS: Chemical Abstracts Service CMR: Carcinogenic, Mutagenic or Toxic for Reproduction Ecxx: Effective Concentration FG: food grade GHS: Harmonized System of Classification and Labeling of Chemicals H-Phrase: H-statement IATA: International Air Transport Association. IATA-DGR: Dangerous Goods Regulation International Air Transport Association ICAO: International Civil Aviation Organization ICAO-TI (ICAO): International Civil Aviation Organization IC: Inhibitory Concentration IMDG: International Maritime Code for Dangerous Goods ISO: International Organization for Standardization LC: Lethal Concentration LD: Lethal Dose logPow: Octanol / water partition coefficient OECD: Organization for Economic Co-operation and Development) AGW: Arbeitsplatzgrenzwert (N.O.S.) PBT: Persistent, bioaccumulative and toxic PEC: Predicted Effect Concentration PEL: Permissible Exposure Limits PNEC: Predicted No Effect Concentration PSA: PersönlicheSchutzausrüstung P-Phrases: P-statement NOEL: No Observed Effect Level NOAEL: No Observed Adverse Effect Level STEL: Short-term exposure limit STOT: Specific Target Organ Toxicity TLV: Threshold Limit Value TWA: Time-weighted average vPvB: Very Persistent and Very Bioaccumulative WEL: Workplace Exposure Level MAK: MaximaleArbeitsstoffkonzentration (maximum workplace concentration) ADNR: Regulation on the transport of dangerous goods on the Rhine ADR: Agreement concerning the International Carriage of Dangerous Goods by Road. CLP: Classification, Labeling and Packaging CSA: Chemical Safety Assessment CSR: Chemical Safety Report DNEL: Derived No Effect Level EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals RID: Concerning the International Transport of Dangerous Goods by Rail WGK: Deutsche Wassergefährdungsklasse (German water hazard class) AUVA: AllgemeineUnfallversicherungsanstalt, Austria FIOH: Finnish Institute of Occupational Health, Finland HSL: Health and Safety Laboratory, Great Britain INRS: Institut National de Rechercheet de Sécurité, France ITM : Institute for Applied Environmental Research, Air Pollution Laboratory, Sweden INSHT: Instituto Nacional de Seguridad e Higieneen el Trabajo, Spain NIOSH: National Institute for Occupational Safety and Health, USA NIOM: Nofer Institute of Occupational Medicine, Poland NFSZ: NemzetiMunkaügyiHivatal, Hungary SUVA: SchweizerischeUnfallversicherung, Switzerland DFG: Deutsche Forschungsgemeinschaft (Senate Commission for the Investigation of Health Hazardsof Chemical Compounds in the Work Area), Germany